Sulphur Isotope Abundance Variations in Sulphides of the Dharwar Craton-Part I: Kalyadi
Abstract
Sulphur isotope abundance variations in chalcopyrite, pyrite and pyrrhotite samples from the sulphide deposits of Kalyadi have been measured with a double-collector mass spectrometer provided with digital ratio recording. The results fall into two groups - one with a near-zero per-mil value and another with a small positive value ∼5"°. Data on coexisting sulphide minerals enable temperatures of deposition to be calculated, these being low ∼250° C. The Ohmoto-procedure is adopted, and the range of δ34S values of the minerals explained by assuming an initial total sulphur δ34STS value and a range of pH and fO2 values that are plotted on an fS2 - fO2 diagram consistent with the stability fields of the minerals.Downloads
Issue
Section
Downloads
Published
How to Cite
References
GARRELS, R. M. and CHRIST, C. L., (1965) 'Solutions, Minerals al/d Equilihria', Harper and Row, New York.
KAJIWARA, Y. and KROUSE, H. R., (1971) Sulphur isotope partitioning in metallic sulphide systems. Can. Jour. Earth Sci., v. 8. p. 1397.
MENON, A. G., (1979) Sulphur isotope and Trace Element Studies on Sulphide Deposits of Dharwar Craton. Unpublished Ph.D. thesis, Indian Inst. SCi., Bangalore.
NIELSEN, H., (1979) Sulphur isotopes. In: Jager E., Hunziker, J. C. (Eds.) 'Lectures in isotope Geology', Springer-Verlag, Berlin.
OHMoro, H., (1972) Systematics of sulphur and carbon isotopes in hydrothermal ore deposits. Econ. Geol., v. 67, p. 551.
RADHAKRISHNA, B. P., (1974) Copper mineralization in Karnataka, India. Jour. Geol. Soc. India, v. 15. p. 31.
RICKE, W., (1964) Preparation von schwefeldioxid zur Massenspektrometrischen Bestimmung des S-Isotopenverhalthisses in naturlichen S-Verbindungen. Z. Anat. Chernie, v. 199, p. 401.
RYE, R. O. and OHMOTO, H., (1974) Sulphur and Carbon isotopes and ore genesis: A review. Econ. Geol., v. 69, p. 826.
SAKAI, H., (1968) Isotopic properties of sulphur compounds in hydrothermal processes. Geochern. Jour., v. 2, p. 29.