Rare Earth Elements and Yttrium Potentials of Neoproterozoic Peralkaline Siwana Granite of Malani Igneous Suite, Barmer District, Rajasthan

Authors

  • Ramgad Minerals and Mining Limited, Baldota Enclaves, Abheraj Baldota Road, Hospet - 583 203
  • Ramgad Minerals and Mining Limited, Baldota Enclaves, Abheraj Baldota Road, Hospet - 583 203

DOI:

https://doi.org/10.1007/s12594-019-1263-0

Abstract

The bimodal volcano-plutonic association of Neoproterozoic Malani Igneous Suite of western Rajasthan has resulted in enrichment of rare earth elements (REE), especially heavy rare earth elements (HREE) due to fractionation during polychronous emplacement of riebeckite / aegirine bearing peralkaline granite in three phases. The modal mineralogy indicates bastnasite (La-Ce), parasite, La-Ce-Ba cebaite, cerianite, thorianite, carbocernaite, ancylite, strontianite, celestire, allanite, fergusonite, REE silicates, xenotime, monazite, REE clays and zircon in order of abundance. The distribution of minerals shows total REE minerals 2.04% in Gudanal (east), 2.23% in Gudanal (west), 2.15% in Meli and 2.5% in Bhatikhera. The end phase of magmatic activity represented by boss, dykes and veins of microgranite has rich potentials for HREE. Out of several blocks having preponderance of dykes/veins, Gudanal (east and west), Bhatikhera, Phulan and Meli areas are most promising. The HREE and yttrium abundance of Gudanal (west) is 0.33%, Gudanal (east), 0.22%, Bhatikhera as 0.31% and Phulan 0.93%. Majority of REE minerals are small in size (< 20 microns) occurring as carbonates, followed by phosphates, oxides and silicates and will warrant detailed bulk mineral processing test for the recovery of REE minerals and subsequent metallurgical tests.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Issue

Section

Research Articles

Published

2019-07-01

How to Cite

Bhushan, S., & Somani, O. (2019). Rare Earth Elements and Yttrium Potentials of Neoproterozoic Peralkaline Siwana Granite of Malani Igneous Suite, Barmer District, Rajasthan. Journal of Geological Society of India, 94(1), 35–41. https://doi.org/10.1007/s12594-019-1263-0

References

Alexander P. Gysi, and Anthony E. Williams- Jones (2013) hydrothermal mobilization of pegmatite- Hosted REE and Zr at Strange Lake, Canada: A reaction Path model. Geochim. Cosmochim. Acta, v.122, pp.324-352

Bailey, D.K. (1964) Crustal Warping - a possible tectonic control of alkali magmatic. Jour. Geophys. Res., v.69, pp.1103-1111.

Bates, R.L. and Jackson, J.A. (1980) Glossary of Geology. AGI, Falls Church, pp.751.

Bhushan, S.K. (1984) Classification of Malani Igneous Suite. Symposium on three decades of developments in petrology, mineralogy and petrochemistry in India, Geol. Surv. India Spec. Publ., v.12, pp.199-2005.

Bhushan, S.K. and Mohanty, M. (1988). Mechanics of intrusion and geochemistry of alkaline granites from Siwana, Barmer district, Rajastahn.Indian Jour. Earth Sci., v.15(2), pp.103-115

Bhushan, S.K. (1978) Volcanic vent in Malani Igneous Suite. Geol. Surv. India News, no.9(2), 2p.

Bhushan, S.K. (1979) Geology of part of district Barmer, Jalor and Sirohi with special reference to Malani Igneous Suite. XIIIth Geology Cource, IPI Dehradun.

Bhushan, S.K. (1984) Classification of Malani igneous Suite. Symposium on Three decades of developments in petrology, mineralogy, and petrochemistry in India. Geol. Surv. India, Spec. Publ., no.12, pp.199205.

Bhushan, S.K. (1988) Mechanics of intrusion and geochemistry of alkaline granites from Siwana, Barmer district, Rajasthan. Indian Jour. Earth Sci., v.15(2), pp.103-115.

Bhushan, S.K. and Chittora, V.K. (1999) Late Proterozoic bimodal volcanic assemblage of Siwana subsidence structure, western Rajasthan, India. Jour.Geol. Soc. India, v.53, pp.pp.433-452.

Bhushan, S.K. and Chandrasekaran, V. (2002) Geology and geochemistry of the magmatic rock of the Malani Igneous Suite and Tertiary Alkaline province of Western Rajasthan. Mem. Geol. Surv. India, v.126, pp.1-181.

Bidwai, R. and Krishnamurthy, P. (1997) Possible lava channels and tubes from the Siwana Caldera Sequence, Siwana, Barmer District, Rajasthan.Jour. Geol. Soc. India, v.50(3), pp.303-305

Bonin, B. Azzouni-Sekkal, A., Bussy, F. and Ferrag, S. (1998) Alkali-calcic and Alkaline Post-Orogenic (PO) Granite Magmatism: petrologic Constraints and Geodynamic setting, v.45, pp.45-70.

Bowden, P. and Whitley, J.E. (1974) Rare – Earth Patterns in Peralkaline and Associated granite. Lithos, v.7(1), pp.15-21

Binnemans, K. (2014) Economics of Rare Earths: the Balance Problem. ERES 2014: 1st European Rare Earth Resources Conference, pp. 37-46.

Cerny, P. and Ercit, T.S. (2005) Classification of granitic pegmatites revisited.Canadian Mineralogist, v.43, pp.2005-2026.

Coulson, A.L. (1933) The Geology of the Sirohi State, Rajputana. Mem. Geol.Surv. India, v.63(1), p166.

Collins, W.J., White, A.J.R. and Chappell, B.W. (1992) Nature and origin of A-type granite with Particular reference to south eastern Australia. Contrib. Mineral. Petrol., v.80, pp.189-200.

Dostal.J. Chatterjee, A.K. and Kontak. D, J. (2004) Chemical and isotopic (Pd, Sr) Zonation in a peraluminous granite pluton: Role of Fluid fractionation: Contrib. Mineral. Petrol., v.147, pp.74-90.

Dostal, J. (2016) Rare metal Deposits associated with alkaline/ Peralkaline Igneous rocks. Soc. Econ. Geologist. Inc., v.18.pp.33-54.

Das, U.K., Gantait, A., Panda, L. and Hussain, S. (2016) Rare earth element potential of the felsite dykes of Phulan area, Siwana ring complex, Rajasthan, India. Curr. Sci., v.110(7), pp.1157-1162.

Fitton, J.G. and Upton, B.G. (1987) Alkaline Igneous Rocks. Geol. Soc. Spec.Publ., v.30, pp.568.

Harris, N.B.W. and Marriner, G.F. (1980) Geochemistry and petrogenesis of a Peralkaline granite complex from the Midian Mountains, Saudi Arabia.Lithos, v.13(4), pp.325-337

Halter, W. and Webster, J.D. (2004) The magmatic to Hydrothermal transition and its bearing on ore-forming systems. Chemical Geol., v.210, pp.1-6.

Jacobson, R.R.F. Mac Leod, W.N. and Black, R. (1958) Ring-complexes in the younger Granite Province of northern Nigeria. Mem. Geol. Soc. London, no.1(1), pp.1-72

Kochhar, N. (1984) The Malani Igneous Suite: Hot spot magmatism and cratonisation of the northern part of the Indian Shield. Jour. Geol. Soc.India, v.25, pp.155-161.

Kochhar, N., Vallinayagam, G. and Gupta, L.N. (1991) Zircon from the granitic rocks of the Malani Igneous Suite: Morphological and chemical studies.Jour. Geol. Soc. India, v.38, pp.561-576.

Kerr, A. and Rafuse, H. (2012) Rare Earth element (REE) Geochemistry of the strange lake deposits: Implications for resource estimation andmetallogenicmodels. Current Res., Newfoundland and Labrador Department of Natural Resources Geol. Surv. Report 12-1, pp.39-60.

Kogarko, L.N. (1990) Ore-forming potential of alkaline magmas. Lithos, v.26, pp.167-175.

LaTouche, T.D.H. (1902) Geology of Western Rajasthan. Mem. Geol. Surv. India, v.35(1), pp.1-116.

Leelanandam, C. (1989) Alkaline Rocks. Mem. Geol. Soc. India, no.15, pp.1311.

Linen. R.L. and Cuney, M. (2005) Granite-related rare-element deposits and experimental constraints on Ta-Nb-W-Sn-Zr-Hf mineralization. Geol.Assoc. Canada short Course Notes, v.17, pp.45-68.

Loiselle, M.C. and Wones, D.R. (1979).Characteristics and origin of anorogenic granites (abs.): Geol. Soc. Amer., v.11, p.468.

Martin, R.F. and Piwinskii, A.J. (1972). Magmatism and tectonic settings. Jour. Geophys. Res., v.77, pp.4966-4975.

Marks, M., Vennemann, T., Siebel, W. and Markl, G. (2003). Quantification of magmatic and Hydrothermal processes in a peralkaline syenite-alkali granite complex based upon textures, phase equilibria, and stable and radiogenic isotopes. Jour. Petrol., v.44, pp.1247-1280.

Markl, G. Marks, M.A.and Frost B.R. (2010) On the controls of oxygen fugacity in the generation and crystallization of peralkaline melts. Jour. Petrol., v.51, pp.1831-1847.

Maheshwari, A. and Sial, A.N. (2001) Geochemistry and petrogenesis of Siwana Peralkaline Granites, West of Barmer, Rajasthan, India. Gondwana Res., v.4(1) pp.87-95.

Mohanty, M. Bhushan, S.K. (2004) Neoproterozoic Peralkaline Siwana granite, Barmer district, Rajasthan and its potential for Rare earth element mineralization. Geol. Surv. India, Spec. Publ., v.72, pp.363-376.

Murthy, M.V.N. and Venkatenaman, P.K. (1964) Petrogenetic significance of certain platform peralkaline granites of the world. The Upper Mantle Symposium. New Delhi, pp.127-149.

Murthy, M.V.N. (1962) The significance of ring pattern of Siwana granitic bosses in Western Rajasthan. Indian Minerals, v.16(8), pp.297-298.

Mukherjee, A.B. and Roy, A. (1981) Colling conditions of high level Precambrian granite of Siwana: Evidence of experimental melting behavior and the sodic amphibole pyroxene reaction relation. Indian Jour. Earth.Sci., v.8(2), pp.99-109.

Nardi, L.V.S. and Bonin, B. (1991) Post-orogenic and non-orogenic alkaline granite associations the Saibro Intrusive Suite, Southern Brazil-a case study. Chemical Geol., v.92, pp.197-212

Pascoe, E.H. (1960) Manual of the geology of India and Burma. Geol. Surv.India, v.2, pp.556-572.

Pearce, J.A., Niger, B.W.H. and Tindle, G. (1984) Trace element discrimination diagrams for the tectonic interpretation of granitic rocks. Jour. Petrol., v.25(4), pp.56-83.

Ratnakar, J. and Leelanandam, C. (1989) Petrology of alkaline plutons from the eastern and southern peninsular India. Mem. Geol. Soc. India, No.15, pp.145-176.

Ratnakar, J. (2007) Lithosphere control of the proterozoic alkaline magmatism: the miaskiticnepthelinesyenites of Southern India. In: C. Leelanandam, I.B.R. Rao, Ch. Sivaji and M. Santosh (Eds.), The Evolution of the Indian Continental Crust and Upper Mantle. Internat., Assoc. Geol. Res. (IAGR) Mem. no.10, pp.109-121.

Richardson, D.G. and Birkett, T.C. (1996) Peralkaline rock-associated rare metals: Geol. Soc Amer., Geology of North America, v.1, pp.523-540.

Rogers, J.W. and Greenberg, J.K. (1981) Trace element in continental margin magmatism Pt.III. Alkali granites and their releationship to cratonization.Bull. Geol. Soc. Amer., v.92(1), pp.6-9.

Sorensen, H. (1974). Alkali Syenites, Feldspathoidalsyenites and Related Lavas.

In: Sorense, H. (Ed.), The alkaline Rocks. Landon: John Wiley& Sons, pp.22-52.

Smith, R.L. and Bailey, R.A. (1968) Resurgent cauldrons. Mem. Geol. Soc, Amer., v.116, pp.613-662.

Salvi, S. and Williams-Jones, A.E. (1990) The role of hydrothermal processes in the granite – hosted Zr, Y, REE deposit at strange Lake,Quebec/ Labrador: Evidence from fluid inclusion: Geochim. Cosmochim. Acta, v.54, pp.2403-2418.

Salvi, S. and Williams-Jones, A.E. (1996) The role of Hydrothermal processes in concentrating HFSE in the Strange Lake peralkaline complex, northeastern Canada: Geochim. et Cosmochim. Acta, v.60, pp.1917-1932.

Salvi, S. and Williams-Jones, A.E. (2005) Alkaline granite-syenite deposits: Geological Association of Canada Short Course Notes, v.17, pp.315-341.

Upton, B.G.J. (1974) The alkaline province of south-west Greenland. In: Sorensen, H. (Ed.). The Alkaline Rocks. Wiley, New York, pp.221-238.

Veksler. I.V. (2004) Liquid immiscibility and its role at the magmatichydrothermal transition: A summary of experimental studies: Chemical Geol., v.210, pp.7-31.

Vorma, A. (1976) On the petrogeochemistry of Rapakivi granites with special reference to the Laitila massif, Southwestern Finland. Bull. Geol. Surv.Finland, pp.285, 98.

White, C.A. (1980) The petrology and geochemistry of Peralkaline granite and volcanic rocks near Davis Inlet, Labrador. Masters thesis, Memorial University of Newfoundland.

Whalen, J.B. Currie, K.L. and Chappell, B.W. (1987). A-type granites: geochemical characteristics, discrimination and petrogenesis. Contrib.Mineral. Petrol., v.95, pp.407-419.