Deuterium Excess of Groundwater as a Proxy for Recharge in an Evaporative Environment of a Granitic Aquifer, South India
Authors
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CSIR - National Geophysical Research Institute, Uppal Road, Hyderabad – 500 007
P. D. Sreedevi -
ICAR - National Academy of Agricultural Research Management, Rajendranagar, Hyderabad – 500 030
P. D. Sreekanth
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CSIR - National Geophysical Research Institute, Uppal Road, Hyderabad – 500 007
D.V. Reddy
DOI:
https://doi.org/10.1007/s12594-021-1740-0Keywords:
No keywords.Abstract
The deuterium excess (d-excess) is a function of the composition of stable isotopes, oxygen (d18O), and deuterium (dD) in water. It contains information about initial moisture source, evaporation effects during monsoon, and recirculation of moisture from large inland water. To meet the objectives of this study, a total of seventytwo groundwater samples were collected from bore wells during the pre and post-monsoon seasons. d-excess values vary from - 52.81 to 2.29 ‰ with a mean of -9.90 ‰ and -60.89 to 9.44 ‰ with a mean of -0.7‰ in the pre and post-monsoon seasons respectively. Based on the d18O concentration groundwater samples are classified into three groups. Group I and II samples having high d-excess with respect to d18O, which indicates the dry conditions in continental local water air and their source of water vapor. Most of the deep groundwater wells (> 20 m bgl) fall under these categories, which indicates low degree of evaporation. Group III samples having low d-excess values and enriched with d18O, indicates that these waters have undergone evaporation to different extents before recharge. Most of the shallow (< 10 m bgl) and moderate groundwater wells (10 – 20 m bgl) fall under this category, indicating high degree of evapotranspiration originated either from unsaturated or saturated zones. The climatic water balance studies also indicate that the annual average potential evapotranspiration (PET) is higher (2131 mm) than the annual average rainfall (662 mm) in the study period. This study reveals that the diffuse rainfall recharge flows are more dominated to recharge the aquifer during the monsoon season and the past/ rainfed recharge flows through preferential pathways along the gradients in the fractured zone are dominated to recharge the aquifer in the post-monsoon season. These processes play a significant role to keep the hydrological balance in areas of high evaporation.
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References
APHA (1992) Standard Methods for the examination of water and wastewater. APHA publication, 18th ed. Washington DC.
Bahir, M., Ouazar, D., Ouhamdouch, S. (2019) Hydrogeochemical mechanisms and recharge mode of the aquifers under semiarid climate from Morocco. Appl. Water Sci., v.9, pp.103.
Balugani, E., Lubczynski, M.W., Reyes-Acosta, L., Van der Tol, C., Frances, A.P., Metselaar, G.K. (2017) Groundwater and unsaturated zone evaporation and transpiration in a semi-arid open woodland. Jour. Hydrol., v.547, pp.54-66.
Ben Cheikh, N., Zouari, K., Abidi, B. (2014) A hydrogeochemical approach for identifying salinization processes in the Cenomanian-Turonian aquifer, south-eastern Tunisia. Carbonates Evaporites v.29(2), pp.193-201.
Carter, R.C., Alkali, A.G. (1996) Shallow groundwater in the northeast arid zone of Nigeria. Quart. Jour. Engg. Geol. Hydrogeol., v.29(4), pp.341-355.
Clark, I., Fritz, I. (1997) Environmental isotopes in hydrogeology. Boca Raton, NY: Lewis Publishers, p.328.
Craig, H. (1961) Isotopic variation in meteoric water. Science v.133, pp.1702- 1703.
Dansgaard, W. (1964) Stable isotopes in precipitation. Tellus, v.16, pp.436- 468.
Francisco, J., Alcala, J.F., Canton, Y., Contreras, S., Were, A., Serrano-Ortiz, P., Puigdefa Bregas, J., Sole-Benet, A., Custodio, E., Domingo, F. (2011) Diffuse and concentrated recharge evaluation using physical and tracer techniques: results from a semiarid carbonate massif aquifer in southeastern Spain. Environ. Earth Sci., v.62(3), pp.541-557.
Fynn, O.F., Yidana, S.M., Chegbeleh, I.P., Yiran, G.B. (2016) Evaluating groundwater recharge processes using stable isotope signatures –The Nabogo catchment of the White Volta, Ghana. Arabian Jour. Geosci., v.9, pp.279
Gee, G.W., Hillel, D. (1988) Groundwater recharge in arid regions: review and critique of estimation methods. Hydrolog. Process., v.2, pp.255-266.
GSI (1995) Geological Quadrangle map 57 F. Printed at Info maps, Madras.
GSI (2004) Geological Quadrangle map 57 E. Printed the map printing division, Hyderabad.
Gupta, S.K., Deshpande, R.D. (2005) Groundwater isotopic investigations in India: What has been learned?. Curr. Sci., v.89(5), pp.825-835.
He, J., Ma, J., Zhang, P., Tian, L., Zhu, G., Edmunda, W.M., Zhang, Q. (2012) Groundwater recharge environments and hydrogeochemical evolution in the Jiuquan Basin, Northwest China. Appl. Geochem. v.27, pp.866-878.
Hendriksson, N., Okkonen, J., Luoma, S. (2019) Deuterium Excess as Tracer for Seasonal Isotope Variations of Precipitation in Surficial Groundwaters. Geological Survey of Finland, (online accessed dated 31.08.2019).
Huang, P., Wang, X. (2017) Applying environmental isotope theory to groundwater recharge in the Jiaozuo mining area, China. Geofluids, article ID 9568349, 11 pages.
Issar, A., Gat, J. (1981) Environmental isotopes as a tool in hydrogeological research in an arid basin. Groundwater, v.19(5), pp.490-494.
Joshi, S.K., Rai, S.P., Sinha, R., Gupta, S., Densmore, A.L., Rawat, Y.S., Shekhar, S. (2018) Tracing groundwater recharge sources in the northwestern Indian alluvial aquifer using water isotopes (d18O, d2H and 3H). Jour. Hydrol., v.559, pp.835-847.
Kohfahl, C., Sostnger, C., Herrer, J.B., Meyer, H., Chacon, F.F., Pekdeger, A. (2008) Recharge sources and hydrogeochemical evolution of groundwater in semiarid and karstic environments: A field study in the Granada Basin (Southern Spain). Appl. Geochem., v.23, pp.846-862.
Kong, Y., Wang, K., Pu, T., Shi, X. (2019) Nonmonsoon precipitation dominates groundwater recharge beneath a monsoon-affected glacier in Tibetan plateau. Jour. Geophys. Res. Atmosph., v.124, pp.10,913-10,930.
Kumar, B., Rai, S.P., Kumar, S.U., Verma, S.K., Garg, P., Kumar, S.V.V., Jaiswal, R., Purendra, B.K., Kumar, S.R., Pande, N.G. (2010) Isotopic characteristics of Indian precipitation. Water Resour. Res., v.46, W12548, doi:10.1029/2009WR008532.
Linhares, G.M.G., Moreira, R.M., Pimenta, R.C., Scarpelli, R.P., Santos dos, E.A. (2017) Stable isotope oxygen-18 and deuterium analysis in surface and groundwater of the Jequitiba Creek basin, Sete Lagoas, MG. Internation Nuclear Atlantic Conference - INAC 2017, Belo Horizonte, MG, Brazil, October 22-27, 2017.
Marechal, J.C., Dewandel, B., Ahmed, S., Lachassagne, P. (2007) Hard-rock aquifers characterization prior to modelling at catchment scale: An application to India. In: Krasny J. and Sharp J.M., (Eds.) , Groundwater in Fractured Rocks. IAH selected papers, Taylor and Francis, London,v.9, pp.1-30.
McCabe, G.J., Markstrom, S.L. (2007) A monthly water-balance model driven by a graphical user interface: USGS Open-File report 2007-1088, 6p.
Mook, W.G. (2001) Environmental isotopes in the hydrological cycle – principles and applications. Vol 1, International hydrological programme (IHP-V). technical documents in hydrology, no.39, UNESCO-IAEA.
Murad, A. (2014) Deuterium excess of groundwater as a proxy for recharge in an evaporative environment. EGU general Assembly, Geophysical Research Abstracts 16: EGU2014-38.
Payne, B.R. (1988) The status of isotope hydrology today. Jour. Hydrol., v.100, pp.207-237.
Pfahl, S., Sodemann, H. (2014) What controls deuterium excess in global precipitation. Climate of the Past, v.10, pp.771-781.
Puntsag, T., Mitchell, M., Campbell, J., Keein, E.S., Likens, G.E., Welker, J.M. (2016) Arctic Vortex changes alter the sources and isotopic values of precipitation in northeastern. US Scientific Report, v.6, pp.22647.
Qu, S., Chen, X., Wang, Y., Shi, P., Shan, S., Gou, S., Jiang, P. (2018) Isotopic characteristics of precipitation and origin of moisture sources in Hemuqiao catchment, a small watershed in the Lower Reach of Yangtze River. Water, v.10(9), pp.170.
Saha, S.D., Dwivedi, S.N., Roy, G.K., Reddy, D.V. (2013) Isotope-base investigation on the groundwater flow and recharge mechanism in a hardrock aquifer system: the case of Ranchi urban area, India. Hydrogeol. Jour., v.21, pp.1101-1115.
Saka D, Akiti TT, Osae S, Appenteng MK, Gibrilla A (2013) Hydrogeochemistry and isotope studies of groundwater in the Ga West Municipal area, Ghana. Appl. Water Sci., v.3, pp.588.
Sami K (1992) Recharge mechanisms and geochemical processes in a semiarid sedimentary basin, Eastern Cape, South Africa. Jour. Hydrol., v.139, pp.27-48.
Samir, A.G. (2011) An assessment of recharge possibility to North-Western Sahara aquifer system (NWSAS) using environmental isotopes. Jour. Hydrol., v.398, pp.184-190.
Shamsuddin, M.K.N., Sulaiman, W.N.A., Ramli, M.F., Kusin, F.M., Samuding, K. (2018) Assessment of seasonal groundwater recharge and discharge using environmental stable isotopes at lower muda river basin, Malaysia. Applied Water Science, v.8, pp.120.
Sreedevi, P.D., Ahmed, S., Reddy, D.V. (2017) Mechanism of Fluoride and Nitrate Enrichment in Hard-rock Aquifers in Gooty Mandal, South India. Environ. Process., v.4(3), pp.625-644.
Thornthwaite, C.W. (1948) An approach toward a rational classification of climate. Geographical Rev., v.38(1), pp.55-94.
Trinidad, J.G., Guerrero, A.P., Ferreira, H.J., Capetillo, C.B., Antonio, A.H. (2017) Identifying groundwater recharge sites through environmental stable isotopes in an alluvial aquifer. Water, v.9, pp.569; doi:10.3390/ w9080569.
Yusuf, M.A., Abiye, T.A., Butler, M.J., Ibrahim, K.O. (2018) Origin and residence time of shallow groundwater resources in lagos coastal basin, South-west Nigeria: An isotopic approach. Heliyon, v.4(11), pp.e00932, doi:10.1016/j.heliyon.2018.e00932.
Zhao, L., Xiao, H., Dong, Z., Xiao, S., Zhou, M., Cheng, G., Yin, Li, Yin, Z. (2012) Origins of groundwater inferred from isotopic patterns of the Badain Jaran desert, Northwestern China. Groundwater, v.50(5), pp.715- 725.
